Kenta, a Pokemon master in the making, meets up with his childhood friend, Marina, at a Pokemon Center, to see how their skills have developed. Their battle is interrupted by a thunderstorm and the arrival of Bashou and Buson, two Rocket-dan members using the Crystal System (which attracts Electric-type Pokemon). Their ultimate goal is to, under the guidance of professor Shiranui, bring Pokemon back to Sakaki. Kenta and Marina stumble upon this plan, and they try to stop it, but things get more difficult when the legendary Pokemon Raikou is captured.

This is the DVD edition of the Tokimeki Memorial Super Live held at Zepp Tokyo on October 26, 2002. From "Tokimeki Memorial" to "Tokimeki Memorial 3: In That Place of Promise", the live performances that responded to the passionate voices of the fans has now been immortalized.

The story begins when the protagonist Hikaru meets aliens Lala, Prunce, and Fuwa while watching the night sky. She learns of the “Star Palace,” where the 12 Star Princesses of the constellations kept the balance of the universe until they were attacked. Lala is searching for the legendary Precure warriors to help find the 12 scattered “Princess Star Color Pens” and revive the princesses. When Fuwa is captured by an enemy, Hikaru wishes to save Fuwa, and a Star Color Pendent and a Star Color Pen appear to allow her to transform into Cure Star. From then on she works to collect the pens and raise Fuwa, who is the key to reviving the princesses.

Nodoka and the others obtain something known as the "Dream Pendant" which gives them the ability to see holographic images of various things in Tokyo. These things vary from fish to animals to sweets!